000 06451cam a2200517 i 4500
001 on1032303160
003 OCoLC
005 20250612155459.0
006 m o d
007 cr cnu|||unuuu
008 180425s2018 ne o 001 0 eng d
010 _a 2020304494
040 _aN$T
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019 _a1032591359
_a1032652919
_a1032720765
_a1033532067
_a1033551782
_a1258395283
020 _a9780128110621
_q(electronic bk.)
020 _a0128110627
_q(electronic bk.)
020 _z9780128110614
020 _z0128110619
035 _a(OCoLC)1032303160
_z(OCoLC)1032591359
_z(OCoLC)1032652919
_z(OCoLC)1032720765
_z(OCoLC)1033532067
_z(OCoLC)1033551782
_z(OCoLC)1258395283
050 4 _aQD474
072 7 _aSCI
_x013040
_2bisacsh
082 0 4 _a547/.050459
_223
100 1 _aKharisov, Boris I.,
_eauthor.
_934137
245 1 0 _aDirect Synthesis of Metal Complexes /
_cBoris Kharisov.
250 _aFirst edition.
264 1 _aAmsterdam, Netherlands :
_bElsevier,
_c[2018]
264 4 _c�2018
300 _a1 online resource
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
588 _aOnline resource; title from PDF title page (EBSCO, viewed April 26, 2018).
500 _aIncludes index.
520 _a"Direct Synthesis of Metal Complexes provides in-depth coverage of the direct synthesis of coordination and organometallic compounds. The work is primarily organized by methods, but also covers highly relevant complexes, such as metal-polymer coordination compounds. This updated reference discusses recent developments in cryosynthesis, electrosynthesis, and tribosynthesis (popular as it doesn't require organic solvents), with special attention paid to 'greener' methodologies and approaches. Additionally, the book describes physical methods of zero-valent metal interaction with organic matter, including sputtering, ultrasonic treatment and synthesis in ionic liquids. The book presents completely new content as a follow-up to the 1999 Elsevier Science publication Direct Synthesis of Coordination and Organometallic Compounds that was edited by Dr. Garnovskii and Dr. Kharisov. Covers current methods and techniques of metal interactions with organic media leading to metal chelates, adducts, di- and polymetallic complexes, metal-containing macrocycles, supported coordination compounds (i.e., metal complexes on carbon nanotubes), and moreDescribes reactivities of distinct forms of elemental metals (powders, sheets, nanoparticles (including a host of less-common metal nanostructures) with organic phase (liquid, solid and gaseous) and waterIncludes experimental procedures, with examples of direct synthesis, at the end of each chapter"--
_cProvided by publisher.
505 0 _aIntro; Title page; Table of Contents; Copyright; Dedication; Contributors; Foreword; Preface; Part 1: History and State of the Art of the "Direct Synthesis" Methods; Educational and Historical Aspects of Direct Synthesis of Metal Complexes; Abstract; 1 Introduction; 2 Historical Development of Direct Synthesis; 3 Pedagogical Value: Why Incorporate Direct Synthesis in the Undergraduate Laboratory?; 4 Ultrasonic and Microwave Mediated Direct Synthesis; 5 Conclusion; Recent Advances in Direct Synthesis of Organometallic and Coordination Compounds; Abstract; Acknowledgment; 1 Indirect Synthesis.
505 8 _a2 Direct Synthesis3 Group I; 4 Group 7; 5 Group 8; 6 Group 9; 7 Group 10; 8 Group 11; 9 Group 12; 10 Group 13; 11 Group 14; 12 Group 15; 13 Group 16; 14 Summary and Outlook; Direct Electrochemical Synthesis of Metal Complexes; Abstract; 1 Basic Concepts; 2 Electrochemical Thermodynamics; 3 Electrochemical Kinetics; 4 Reaction Mechanisms; 5 Electrochemical Cells; 6 Solvents and Supporting Electrolytes; 7 Metals; 8 Ligands; 9 Conclusions and Further Outlook; Cryochemical Co-condensation of Metal Vapors and Organic Compounds; Abstract; 1 Introduction.
505 8 _a2 Formation of Metal Organosols Under the Low-temperature Vapor Co-condensation3 Preparation of Metal-Organic Compounds via the Metal-Vapor Cryosynthesis; 4 Synthesis of Catalysts by Low-temperature Co-condensation of Metal Vapors and Organic Compounds; 5 Conclusions; Part 2: "Direct" Methods in the Preparation of Distinct Types of Complexes; Direct Synthesis of Heterometallic Complexes; Abstract; 1 Introduction; 2 Salt Route; 3 Ammonium Salt Route; 4 Conclusions; New Trends in the Direct Synthesis of Phthalocyanine/Porphyrin Complexes; Abstract; Acknowledgments; 1 Introduction.
505 8 _a2 Classical Approach of Phthalocyanine/Porphyrin Complexes Direct Synthesis3 New Methods of Phthalocyanine/Porphyrin Complexes Direct Synthesis; Increasing the Rate of the Direct Synthesis Complex Compounds; Abstract; 1 The Accumulation of Metallic Elements in the Technological Waste; 2 The Use of Direct Synthesis of Complex Compounds for Extraction of Metallic Elements from Industrial Waste; 3 Effect on the Rate, Selectivity, and Yield of the Donor-Acceptor Interaction Product of a Number of Physical and Chemical Factors.
505 8 _a4 Accelerate the Direct Synthesis of Complex Compounds When Moving and Delivery of the Ligand Molecule in the Surfactant Micelles5 Effect of Porous Silica on Coordinating the Interaction; 6 Contact the Kinetic Characteristics of the Direct Synthesis of Complex Connections with the Debye Temperature of the Metal and Coefficient Gr�uneisen; Part 3: "Direct Synthesis" and Nanotechnology; Direct Synthesis of Nanomaterials: Building Bridges Between Metal Complexes and Nanomaterials; Abstract; 1 Introduction; 2 Analogies Among Metal Complexes and Nanomaterials; 3 Direct Synthesis of Nanomaterials.
504 _aIncludes bibliographical references and index.
650 0 _aCoordination compounds
_xSynthesis.
_934138
650 0 _aOrganometallic compounds
_xSynthesis.
_934139
758 _ihas work:
_aDirect Synthesis of Metal Complexes (Text)
_1https://id.oclc.org/worldcat/entity/E39PCGQFPkdX7jgRCv6KjCBy7d
_4https://id.oclc.org/worldcat/ontology/hasWork
776 0 8 _iPrint version:
_z0128110619
_z9780128110614
_w(OCoLC)1010666799
856 4 0 _3ScienceDirect
_uhttps://www.sciencedirect.com/science/book/9780128110614
999 _c216458
_d216458