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015 _aGBB7M8973
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016 7 _a018625514
_2Uk
019 _a1018458304
_a1105178240
_a1105559574
_a1151704523
_a1229538117
020 _a9780128136096
_q(electronic bk.)
020 _a012813609X
_q(electronic bk.)
020 _z9780128136089
020 _z0128136081
035 _a(OCoLC)1018307524
_z(OCoLC)1018458304
_z(OCoLC)1105178240
_z(OCoLC)1105559574
_z(OCoLC)1151704523
_z(OCoLC)1229538117
050 4 _aQC762
072 7 _aSCI
_x038000
_2bisacsh
082 0 4 _a538/.36
_223
100 1 _aKarunakaran, Chandran,
_eauthor.
_1https://id.oclc.org/worldcat/entity/E39PCjGTYyMxxpfP98tqpjxfYP
_934050
245 1 0 _aSpin resonance spectroscopy :
_bprinciples and applications /
_cChandran Karunakaran.
264 1 _aAmsterdam, Netherlands :
_bElsevier,
_c[2018]
300 _a1 online resource :
_billustrations (some color)
336 _atext
_btxt
_2rdacontent
337 _acomputer
_bc
_2rdamedia
338 _aonline resource
_bcr
_2rdacarrier
588 0 _aVendor-supplied metadata.
504 _aIncludes bibliographical references and index.
520 _aSpin Resonance Spectroscopy: Principles and Applications presents the principles, recent advancements and applications of nuclear magnetic resonance (NMR) and electron paramagnetic resonance (EPR) in a single multi-disciplinary reference. Spin resonance spectroscopic techniques through NMR and EPR are widely used by chemists, physicists, biologists and medicinal chemists. This book addresses the need for new spin resonance spectroscopy content while also presenting the principles, recent advancements and applications of NMR and EPR simultaneously. Ideal for researchers and students alike, the book provides a single source of NMR and EPR applications using a dynamic, holistic and multi-disciplinary approach.
505 0 _a<P><b>Unit 1: Principle NMR and pulsed NMR </b>Introduction -- Spin Magnetic properties -- Resonance condition -- Larmor Frequency -- NMR instrumentation -- comparison of NMR & EPR -- chemical shift -- spin-spin coupling -- Coupling constant -- first and second order spectra -- simplification of complex spectra -- Boltzmann Statistics -- Pulsed NMR -- Basic principle of FT technique -- Relaxation process -- Bloch equations -- Relaxation times -- Line shape and line width analysis</p> <p><b>Unit 2: 1H and 13C NMR spectroscopy </b> Interpretation of 1H NMR -- assignment of signals -- influence of factors on chemical shift of protons -- 13C NMR -- spin decoupling -- double resonance -- Nuclear Overhauser Effect -- Off Resonance Decoupling -- CIDNP -- 13C assignment of signals -- additivity rule -- calculation of chemical shifts for aromatic and aliphatic compounds -- 2D NMR -- DEPT 13C -- 13C correlation COSY, HETCOR, NOE & NOSEY- multidimensional NMR</p> <p><b>Unit 3: Applications of NMR </b>Applications of 31P, 19F and 15N -- NMR spectroscopy used in structural problem -- NMR of fluxional molecules -- evaluation of rate constants -- solid state NMR -- magic angle spinning -- NMR of paramagnetic molecules -- contact shifts and shift reagents -- NMR imaging -- contrast agents</p> <p><b>Unit 4: EPR Spectroscopy </b>Principle of EPR -- instrumentation -- total spin Hamiltonian -- presentation of the spectrum -- hyperfine splitting -- super hyperfine structure -- EPR of hydrogen atom -- splitting in isotropic systems involving more than one nucleus -- EPR spectra of free radicals in solution -- methyl radical, benzene anion, p-benzosemiquinone radical anion, p- nitrobenzoate dianion and naphthalene anion -- Evaluation of g and A tensors -- factors affecting the magnitude of g values -- anisotropy -- zero field splitting -- Kramer's theory & degeneracy -- triplet EPR</p> <p><b>Unit 5: Application and advanced EPR </b>Application of EPR in transition metal complexes VO2+ Fe3+ Co2+, Mn2+, Ni2+ and bis-salicylaldimine copper (II) -- Jahn-Teller theory & distortion studies in Cu(II) complexes -- evaluation of spin -- orbital coupling constant -- exchange coupled EPR -- multi resonance EPR -- cw and pulsed EPR and ENDOR -- MEMS and DAVIS -- ESEEM -- HYSCORE -- ESR Spin trapping -- spin labeling -- EPR imaging</p>
650 0 _aNuclear magnetic resonance.
650 0 _aElectron paramagnetic resonance.
650 0 _aElectron paramagnetic resonance spectroscopy.
_934052
758 _ihas work:
_aSpin resonance spectroscopy (Text)
_1https://id.oclc.org/worldcat/entity/E39PCFBpbRxV6h6vhWgrwhYXVC
_4https://id.oclc.org/worldcat/ontology/hasWork
776 0 8 _iPrint version:
_z0128136081
_z9780128136089
_w(OCoLC)991755695
856 4 0 _3ScienceDirect
_uhttps://www.sciencedirect.com/science/book/9780128136089
999 _c216431
_d216431