000 | 00359nam a2200133Ia 4500 | ||
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999 |
_c186373 _d186373 |
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020 | _a9783527335947 | ||
040 | _cCUS | ||
082 |
_a547.2 _bSIN/R |
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100 | _aSingh, Maya Shankar. | ||
245 | 0 |
_aReactive Intermediates in organic chemistry: structure, mechanism, and reactions/ _cMaya Shankar Singh |
|
260 |
_aWeinheim: _bWiley-VCH, _c2014. |
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300 |
_ax, 283 p. : _bill. ; _c25 cm. |
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505 | _aPreface 1 Introduction Reaction Mechanism and Reaction Arrows Properties and Characteristics of a Reaction Summary 2 Carbocations Introduction History Sturctures and Geometry of Carbocations Generation of Carbocation Carbocation Stability Detection of Carbocations Fate of Carbocations Nonclassical Carbocations Radical Cations Summary 3 carbanions Structure and Geometry of Carbanions Generation of Carbanions Stability of Carbanions Reactions of Carbanions Enolate Reactions with Carbonyl Groups Rearrangements of Carbanions Chiral Carbanions Carbanions and Tautomerism Summary 4 Radicals Introduction Detection and Characterization of Radicals Structure and Bonding of Radicals Generation of Free Radicals Stability of Radicals Reactions of Free Radicals Stereochemistry of Radical Reactions Biradicals Summary 5 Carbenes Structure and Geometry of Carbenes Generation of Carbenes Reactions of Carbenes Carbenes and Carbene Ligands in Organometallic Chemistry Summary 6 Niternes ntroduction Structure and Reactivity Generation of Nitrenes Reactions of Nitrenes Summary 7 Miscellaneous intermediates Arynes Ketenes and Cumulenes ortho-Quinone Methides Zwitterions and Dipoles Antiaromatic Systems Tetrahedral Intermediates Summary Index | ||
650 | _aIntermediates (Chemistry) | ||
650 | _aPhysical organic chemistry | ||
650 | _aChemical reactions | ||
942 | _cWB16 |