| 000 | 01449pam a22003374a 4500 | ||
|---|---|---|---|
| 999 |
_c167790 _d167790 |
||
| 020 | _a0471498483 (alk. paper) | ||
| 020 | _a0471498491 (paper : alk. paper) | ||
| 040 | _cCUS | ||
| 082 | 0 | 4 |
_a541.39 _bADA/C |
| 100 | 1 | _aAdams, Dave J. | |
| 245 | 1 | 0 |
_aChemistry in alternative reaction media/ _cDave J. Adams, Paul J. Dyson, and Stewart J. Tavener. |
| 260 |
_aChichester, West Sussex, England ; _aHoboken, NJ : _bJ. Wiley, _cc2004. |
||
| 300 |
_axvi, 251 p. ; _bill. (some col.) ; _c24 cm. |
||
| 504 | _aIncludes bibliographical references and index. | ||
| 505 | _aChemistry in Alternative Reaction Media -- Economic and Political Considerations -- Why Do Things Dissolve? -- Solvent Properties and Solvent Classification -- Density -- Mass Transport -- Boiling Point, Melting Point and Volatility -- Solvents as Heat-Transfer Media -- Cohesive Pressure, Internal Pressure, and Solubility Parameter -- Solvent Polarity -- Dipole Moment and Dispersive Forces -- Dielectric Constant -- Electron Pair Donor and Acceptor Numbers -- Empirical Polarity Scales -- E[superscript N subscript T] and E[subscript T](30) Parameters -- Kamlet--Taft Parameters -- Hydrogen Bond Donor (HBD) and Hydrogen Bond Acceptor (HBA) Solvents -- The Effect of Solvent Polarity on Chemical Systems -- The Effect of Solvent Polarity on Chemical Reactions -- The Effect of Solvent Polarity on Equilibria -- What is Required from Alternative Solvent Strategies? -- Multiphasic Solvent Systems -- An Introduction to Multiphasic Chemistry -- The Traditional Biphasic Approach -- Temperature Dependent Solvent Systems -- Single- to Two-Phase Systems -- Multiphasic Systems -- Solvent Combinations -- Water -- Fluorous Solvents -- Ionic Liquids -- Supercritical Fluids and Other Solvent Combinations -- Benefits and Problems Associated with Multiphasic Systems -- Partially Miscible Liquids -- Kinetics of Homogeneous Reactions -- Rate is Independent of Stoichiometry -- Rate is Determined by the Probability of Reactants Meeting -- Rate is Measured by the Concentration of the Reagents -- Catalysed Systems -- Kinetics of Biphasic Reactions. | ||
| 650 | 0 | _aSolvents. | |
| 650 | 0 | _aSolvation. | |
| 650 | 0 | _aChemical reactions. | |
| 650 | 0 | _aChemical kinetics. | |
| 700 | 1 | _aDyson, Paul J. | |
| 700 | 1 | _aTavener, Stewart J. | |
| 942 | _cSC79 | ||