TY  - BOOK
AU  - Adams,Dave J.
AU  - Dyson,Paul J.
AU  - Tavener,Stewart J.
TI  - Chemistry in alternative reaction media
SN  - 0471498483 (alk. paper)
U1  - 541.39  
PY  - 2004///
CY  - Chichester, West Sussex, England, Hoboken, NJ
PB  - J. Wiley
KW  - Solvents
KW  - Solvation
KW  - Chemical reactions
KW  - Chemical kinetics
N1  - Includes bibliographical references and index; Chemistry in Alternative Reaction Media -- Economic and Political Considerations -- Why Do Things Dissolve? -- Solvent Properties and Solvent Classification -- Density -- Mass Transport -- Boiling Point, Melting Point and Volatility -- Solvents as Heat-Transfer Media -- Cohesive Pressure, Internal Pressure, and Solubility Parameter -- Solvent Polarity -- Dipole Moment and Dispersive Forces -- Dielectric Constant -- Electron Pair Donor and Acceptor Numbers -- Empirical Polarity Scales -- E[superscript N subscript T] and E[subscript T](30) Parameters -- Kamlet--Taft Parameters -- Hydrogen Bond Donor (HBD) and Hydrogen Bond Acceptor (HBA) Solvents -- The Effect of Solvent Polarity on Chemical Systems -- The Effect of Solvent Polarity on Chemical Reactions -- The Effect of Solvent Polarity on Equilibria -- What is Required from Alternative Solvent Strategies? -- Multiphasic Solvent Systems -- An Introduction to Multiphasic Chemistry -- The Traditional Biphasic Approach --  Temperature Dependent Solvent Systems -- Single- to Two-Phase Systems -- Multiphasic Systems -- Solvent Combinations -- Water -- Fluorous Solvents -- Ionic Liquids -- Supercritical Fluids and Other Solvent Combinations -- Benefits and Problems Associated with Multiphasic Systems -- Partially Miscible Liquids -- Kinetics of Homogeneous Reactions -- Rate is Independent of Stoichiometry -- Rate is Determined by the Probability of Reactants Meeting -- Rate is Measured by the Concentration of the Reagents -- Catalysed Systems -- Kinetics of Biphasic Reactions
ER  -