Chapter 1 The Physical Properties of Gases 1 (47) A IDEAL GASES 2 (17) 1-1 Boyle's Law 2 (5) 1-2 Temperature-Volume 7 (3) 1-3 PV= nRT 10 (6) 1-4 Gas Mixtures 16 (3) B NONIDEAL GASES 19 (29) 1-5 Real-Gas PVT 19 (3) 1-6 Critical Point 22 (5) 1-7 Van der Waals' Equation 27 (5) 1-8 Van der Waals' Equation and the Critical Point 32 (3) 1-9 Van der Waals' Equation and the Virial Equation 35 (4) 1-10 Molecular Interactions 39 (9) Chapter 2 The Molecular Theory of Gases 48 (52) A CLASSICAL KINETIC-MOLECULAR THEORY OF GASES 49 (11) 2-1 Kinetic-Molecular Theory 49 (4) 2-2 Molecular Energies and Speeds 53 (3) 2-3 Categories of Molecular Energies 56 (4) B INTRODUCTION TO THE QUANTUM THEORY 60 (14) 2-4 Particle Waves and the de Broglie Wave Equation 60 (4) 2-5 Allowed Translational Energies--One Dimension 64 (4) 2-6 Allowed Translational Energies--Three Dimensions 68 (2) 2-7 Quantized Rotational, Vibrational, and Electronic Energies 70 (4) C DISTRIBUTION OVER QUANTUM STATES 74 (26) 2-8 The Boltzmann Distribution 74 (5) 2-9 One-Dimensional Translational Motion: Distribution over Quantum States, Energies, and Speeds 79 (5) 2-10 Three-Dimensional Translational Motion: Distribution over Quantum States, Energies, and Speeds 84 (4) 2-11 Thermal Energies of the Molecules of a Gas 88 (12) Chapter 3 Energy of Chemical Systems: The First Law of Thermodynamics 100
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Chemistry, Physical and theoretical Chemistry Boyle's Law