TY - BOOK TI - High- resolution NMR techniques in organic chemistry SN - 0080427995 U1 - 547 PY - 1999/// CY - Amsterdam PB - Pergamon N1 - Front Cover -- High-Resolution NMR Techniques in Organic Chemistry -- Copyright Page -- Table of Contents -- Preface to Second Edition -- Preface to First Edition -- Chapter 1. Introduction -- 1.1. The development of high-resolution NMR -- 1.2. Modern high-resolution NMR and this book -- 1.3. Applying modern NMR techniques -- References -- Chapter 2. Introducing high-resolution NMR -- 2.1. Nuclear spin and resonance -- 2.2. The vector model of NMR -- 2.3. Time and frequency domains -- 2.4. Spin relaxation -- 2.5. Mechanisms for relaxation -- References. Chapter 3. Practical aspects of high-resolution NMR -- 3.1. An overview of the NMR spectrometer -- 3.2. Data acquisition and processing -- 3.3. Preparing the sample -- 3.4. Preparing the spectrometer -- 3.5. Spectrometer calibrations -- 3.6. Spectrometer performance tests -- References -- Chapter 4. One-dimensional techniques -- 4.1. The single-pulse experiment -- 4.2. Spin decoupling methods -- 4.3. Spectrum editing with spin-echoes -- 4.4. Sensitivity enhancement and spectrum editing -- 4.5. Observing quadrupolar nuclei -- References. Chapter 5. Correlations through the chemical bond I: Homonuclear shift correlation -- 5.1. Introducing two-dimensional methods -- 5.2. Correlation spectroscopy (COSY) -- 5.3. Practical aspects of 2D NMR -- 5.4. Coherence and coherence transfer -- 5.5. Gradient-selected spectroscopy -- 5.6. Alternative COSY sequences -- 5.7. Total correlation spectroscopy (TOCSY) -- 5.8. Correlating dilute spins with INADEQUATE -- 5.9. Correlating dilute spins with ADEQUATE -- References -- Chapter 6. Correlations through the chemical bond II: Heteronuclear shift correlation -- 6.1. Introduction. 6.2. Sensitivity -- 6.3. Heteronuclear single-bond correlation spectroscopy -- 6.4. Heteronuclear multiple-bond correlation spectroscopy -- 6.5. Heteronuclear X-detected correlation spectroscopy -- 6.6. Heteronuclear X-Y correlations -- References -- Chapter 7. Separating shifts and couplings: J-resolved spectroscopy -- 7.1. Introduction -- 7.2. Heteronuclear J-resolved spectroscopy -- 7.3. Homonuclear J-resolved spectroscopy -- 7.4. 'Indirect' homonuclear J-resolved spectroscopy -- References -- Chapter 8. Correlations through space: The nuclear Overhauser effect -- 8.1. Introduction. 8.2. Definition of the NOE -- 8.3. Steady-state NOEs -- 8.4. Transient NOEs -- 8.5. Rotating-frame NOEs -- 8.6. Measuring steady-state NOEs: NOE Difference -- 8.7. Measuring transient NOEs: NOESY -- 8.8. Measuring rotating-frame NOEs: ROESY -- 8.9. Measuring heteronuclear NOEs -- 8.10. Experimental considerations -- References -- Chapter 9. Diffusion NMR spectroscopy -- 9.1. Introduction -- 9.2. Measuring self-diffusion by NMR -- 9.3. Practical aspects of diffusion NMR spectroscopy -- 9.4. Applications of diffusion NMR spectroscopy -- 9.5. Hybrid diffusion sequences -- References ER -