Reactive Intermediates in organic chemistry: structure, mechanism, and reactions/ Maya Shankar Singh
Material type: TextPublication details: Weinheim: Wiley-VCH, 2014Description: x, 283 p. : ill. ; 25 cmISBN: 9783527335947Subject(s): Intermediates (Chemistry) | Physical organic chemistry | Chemical reactions DDC classification: 547.2Item type | Current library | Call number | Status | Date due | Barcode | Item holds |
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General Books | Central Library, Sikkim University General Book Section | 547.2 SIN/R (Browse shelf(Opens below)) | Available | P41387 |
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Preface
1 Introduction
Reaction Mechanism and Reaction Arrows
Properties and Characteristics of a Reaction
Summary
2 Carbocations
Introduction
History
Sturctures and Geometry of Carbocations
Generation of Carbocation
Carbocation Stability
Detection of Carbocations
Fate of Carbocations
Nonclassical Carbocations
Radical Cations Summary
3 carbanions
Structure and Geometry of Carbanions
Generation of Carbanions
Stability of Carbanions
Reactions of Carbanions
Enolate Reactions with Carbonyl Groups
Rearrangements of Carbanions
Chiral Carbanions
Carbanions and Tautomerism Summary
4 Radicals
Introduction
Detection and Characterization of Radicals
Structure and Bonding of Radicals
Generation of Free Radicals
Stability of Radicals
Reactions of Free Radicals
Stereochemistry of Radical Reactions
Biradicals Summary
5 Carbenes
Structure and Geometry of Carbenes
Generation of Carbenes
Reactions of Carbenes
Carbenes and Carbene Ligands in Organometallic Chemistry
Summary
6 Niternes
ntroduction
Structure and Reactivity
Generation of Nitrenes
Reactions of Nitrenes
Summary
7 Miscellaneous intermediates
Arynes
Ketenes and Cumulenes
ortho-Quinone Methides
Zwitterions and Dipoles
Antiaromatic Systems
Tetrahedral Intermediates
Summary
Index
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