Low-dimensional molecular metals/ Naoki Toyota, Michael Lang, Jens Müller.

By: Toyota, NaokiContributor(s): Lang, Michael | Müller, JensMaterial type: TextTextPublication details: Berlin : Springer, c2007Description: xvii, 300 p. : ill. ; 24 cmISBN: 9783540495741 (hbk.); 3540495746 (hbk.)Subject(s): Conducting polymers | One-dimensional conductors | Molecular electronicsDDC classification: 539.9
Contents:
2 Basic Concepts .... ...... ..... .... .... 7 2.1 Charge Tansfer ......... 7 2.2 Molecular Orbitals and Transfer Integrals .............. 8 3 Structural Aspects . . . . . .................. . . , 13 3.1 Molecular Building Blocks ............13 3.2 Crystal Structures ................... ........ . 16 3.2.1 Quasi-One-Dimensional Compounds ............. 16 3.2.2 Quasi-Two-Dimensional Compounds ............. 19 3.2.3 Three-dimensional Compounds.. . ......... 25 3 3 Anion Ordering and Glassy Phenomena .............. 29 4 Normal-State Properties ..... ............. . 37 4.1 light-Binding Model .. ... .... ... ............ . 37 4.2 Fermi Surfaces and Low Dimensionality . ...... ....... 42 4 3 Electronic Properties ..... ............. . . 45 4.3.1 Transport and Optical Properties .... ....... . 45 4.3.2 Thermal and Magnetic Properties ............. . 63 4.4 Instabilities Involving Spin- and Charge-Degrees of Freedom 75 4.4.1 Charge- and Spin-Density-Waves ................. 75 4 4.2 Spin-Peierls State .................. ........ . 81 4 .43 Charge-Ordering Phenomena ................... 83 4.5 Many-Body Effects .................... 87 4.6 Phase Diagrams .... ....... ........... . 91 5 Magnetic-Field Effects .,,... ....... 99 5.1 Electron Motion in Magnetic Fields . ..... ... .. 100 5.1 1 Semi-Classical Description in k-Space .. ..... 100 5.1.2 Angular-Dependent Magnetoresistance Oscillations , 1.01 5 1.3 Magneto-Optic Resonances ... ......... . 106 5.2 Magnetic Quantum Oscillations ..... ..... ....... 109 5.2.1 Landau Levels and Lifshitz-Kosevich Theory ....... 109 5.2.2 Magnetic Breakdown and Quantum Interference...... 117 5.2.3 Two-Dimensionality EffectI .......... ... .... 120 5.2.4 Superconducting Vortex Stiaes. 123 S.2.5 Magnetic Exchange-Interaction 126 5.3 High-Magnetic Field States ..... ........ . ..... 128 5 3.1 Field-Induced Cascade Transitions to SDWs and Anomalous High-Field States . .......... 128 5.3.2 Field-Induced Destruction of CDW and Anomalous High-Field States .. .. ..... . 33 5.3.3 Approaching the Quantum Limit ..... ...........138 6 Superconductivity ....... ... .. .... .. .... . ... . . 141 6.1 Occurrence of Superconductivity in Molecular Metals ...... 141 6 2 Ginzburg-Landau Theory ............. ....... ... 143 6.3 The Superconducting Phase Transition ..... ..... ... 147 6.3.1 Anisotropy and Superconducting Fluctuations .......148 6.3.2 Pressure Dependence of T' . ............. . ... 153 6.3.3 Disorder ............. ................. . . . 157 6.4 Superconducting Parameters .. . . .. ..... . ... ... 164 6.4.1 (TM TSF)2X .. . . ....... ........... . 165 64.2 (BEDT-TTF)2X and (BEDT-TSF)2X ....1..... . 166 6.5 The Superconducting Mixed State . ...... ........ 170 6.5.1 Overview . ... .. . .. . .. . . . ..... . .... . 170 6.5.2 Basic Concepts of Vortex Matter in Quasi-Two-Dimensional Systems .. ...... 172 6.5.3 Experimental Findings for (BEDT-TTF)2X........ 175 6.6 Superconducting Order-Parameter ... ........ ..... ... 188 6.7 On the Pairing Mechanism .... .. .. .. .. .... . 210 7 Phenomena of Interacting Tr and d-Electrons .........219 7.1 (DCNQI)2Cu .. ............. ... .. .. . . . 219 7.1.1 Crystal Structure and Electrical Conductivity ........ 219 7.1.2 Reentrant Metal-Insulator Transition ......... . 221 7.2 (BEDT-TSF)2FeX4 (X=CI,Br) . . ........... ....... 224 7.2.1 Crystal Structures and Transfer Integrals ....... 225 7.2.2 Conductivity and Magnetism ............ . ..... 227 7.2.3 Magnetic Interactions and Mean-Field Theories .... 229 7.2 4 Anomalous Metallic States ............ . .. . .. 232 7.2 5 Antiferromagnetic Insulating States ..... ..... .... 236 7.2.6 Magnetic Field-Induced Transitions ........... 241
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Holdings
Item type Current library Call number Status Notes Date due Barcode Item holds
General Books Science Library General Books Science Library Science Library, Sikkim University
Science Library General Section
539.9 TOY/L (Browse shelf(Opens below)) Available Books For SU Science Library P19139
Total holds: 0

Includes bibliographical references (p. [249]-289) and index.

2 Basic Concepts .... ...... ..... .... .... 7
2.1 Charge Tansfer ......... 7
2.2 Molecular Orbitals and Transfer Integrals .............. 8

3 Structural Aspects . . . . . .................. . . , 13
3.1 Molecular Building Blocks ............13
3.2 Crystal Structures ................... ........ . 16
3.2.1 Quasi-One-Dimensional Compounds ............. 16
3.2.2 Quasi-Two-Dimensional Compounds ............. 19
3.2.3 Three-dimensional Compounds.. . ......... 25
3 3 Anion Ordering and Glassy Phenomena .............. 29

4 Normal-State Properties ..... ............. . 37
4.1 light-Binding Model .. ... .... ... ............ . 37
4.2 Fermi Surfaces and Low Dimensionality . ...... ....... 42
4 3 Electronic Properties ..... ............. . . 45
4.3.1 Transport and Optical Properties .... ....... . 45
4.3.2 Thermal and Magnetic Properties ............. . 63
4.4 Instabilities Involving Spin- and Charge-Degrees of Freedom 75
4.4.1 Charge- and Spin-Density-Waves ................. 75
4 4.2 Spin-Peierls State .................. ........ . 81
4 .43 Charge-Ordering Phenomena ................... 83
4.5 Many-Body Effects .................... 87
4.6 Phase Diagrams .... ....... ........... . 91

5 Magnetic-Field Effects .,,... ....... 99
5.1 Electron Motion in Magnetic Fields . ..... ... .. 100
5.1 1 Semi-Classical Description in k-Space .. ..... 100
5.1.2 Angular-Dependent Magnetoresistance Oscillations , 1.01
5 1.3 Magneto-Optic Resonances ... ......... . 106
5.2 Magnetic Quantum Oscillations ..... ..... ....... 109
5.2.1 Landau Levels and Lifshitz-Kosevich Theory ....... 109
5.2.2 Magnetic Breakdown and Quantum Interference...... 117
5.2.3 Two-Dimensionality EffectI .......... ... .... 120
5.2.4 Superconducting Vortex Stiaes. 123
S.2.5 Magnetic Exchange-Interaction 126
5.3 High-Magnetic Field States ..... ........ . ..... 128
5 3.1 Field-Induced Cascade Transitions to SDWs
and Anomalous High-Field States . .......... 128
5.3.2 Field-Induced Destruction of CDW
and Anomalous High-Field States .. .. ..... . 33
5.3.3 Approaching the Quantum Limit ..... ...........138

6 Superconductivity ....... ... .. .... .. .... . ... . . 141
6.1 Occurrence of Superconductivity in Molecular Metals ...... 141
6 2 Ginzburg-Landau Theory ............. ....... ... 143
6.3 The Superconducting Phase Transition ..... ..... ... 147
6.3.1 Anisotropy and Superconducting Fluctuations .......148
6.3.2 Pressure Dependence of T' . ............. . ... 153
6.3.3 Disorder ............. ................. . . . 157
6.4 Superconducting Parameters .. . . .. ..... . ... ... 164
6.4.1 (TM TSF)2X .. . . ....... ........... . 165
64.2 (BEDT-TTF)2X and (BEDT-TSF)2X ....1..... . 166
6.5 The Superconducting Mixed State . ...... ........ 170
6.5.1 Overview . ... .. . .. . .. . . . ..... . .... . 170
6.5.2 Basic Concepts of Vortex Matter
in Quasi-Two-Dimensional Systems .. ...... 172
6.5.3 Experimental Findings for (BEDT-TTF)2X........ 175
6.6 Superconducting Order-Parameter ... ........ ..... ... 188
6.7 On the Pairing Mechanism .... .. .. .. .. .... . 210

7 Phenomena of Interacting Tr and d-Electrons .........219
7.1 (DCNQI)2Cu .. ............. ... .. .. . . . 219
7.1.1 Crystal Structure and Electrical Conductivity ........ 219
7.1.2 Reentrant Metal-Insulator Transition ......... . 221
7.2 (BEDT-TSF)2FeX4 (X=CI,Br) . . ........... ....... 224
7.2.1 Crystal Structures and Transfer Integrals ....... 225
7.2.2 Conductivity and Magnetism ............ . ..... 227
7.2.3 Magnetic Interactions and Mean-Field Theories .... 229
7.2 4 Anomalous Metallic States ............ . .. . .. 232
7.2 5 Antiferromagnetic Insulating States ..... ..... .... 236
7.2.6 Magnetic Field-Induced Transitions ........... 241

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