Spin resonance spectroscopy : (Record no. 216431)
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| 000 -LEADER | |
|---|---|
| fixed length control field | 05157cam a2200457 i 4500 |
| 040 ## - CATALOGING SOURCE | |
| Transcribing agency | N$T |
| 019 ## - | |
| -- | 1018458304 |
| -- | 1105178240 |
| -- | 1105559574 |
| -- | 1151704523 |
| -- | 1229538117 |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| International Standard Book Number | 9780128136096 |
| 020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
| International Standard Book Number | 012813609X |
| 100 1# - MAIN ENTRY--PERSONAL NAME | |
| Personal name | Karunakaran, Chandran, |
| 245 10 - TITLE STATEMENT | |
| Title | Spin resonance spectroscopy : |
| Sub title | principles and applications / |
| Statement of responsibility, etc. | Chandran Karunakaran. |
| 300 ## - DESCRIPTION | |
| Extent | 1 online resource : |
| 505 0# - FORMATTED CONTENTS NOTE | |
| Formatted contents note | <P><b>Unit 1: Principle NMR and pulsed NMR </b>Introduction -- Spin Magnetic properties -- Resonance condition -- Larmor Frequency -- NMR instrumentation -- comparison of NMR & EPR -- chemical shift -- spin-spin coupling -- Coupling constant -- first and second order spectra -- simplification of complex spectra -- Boltzmann Statistics -- Pulsed NMR -- Basic principle of FT technique -- Relaxation process -- Bloch equations -- Relaxation times -- Line shape and line width analysis</p> <p><b>Unit 2: 1H and 13C NMR spectroscopy </b> Interpretation of 1H NMR -- assignment of signals -- influence of factors on chemical shift of protons -- 13C NMR -- spin decoupling -- double resonance -- Nuclear Overhauser Effect -- Off Resonance Decoupling -- CIDNP -- 13C assignment of signals -- additivity rule -- calculation of chemical shifts for aromatic and aliphatic compounds -- 2D NMR -- DEPT 13C -- 13C correlation COSY, HETCOR, NOE & NOSEY- multidimensional NMR</p> <p><b>Unit 3: Applications of NMR </b>Applications of 31P, 19F and 15N -- NMR spectroscopy used in structural problem -- NMR of fluxional molecules -- evaluation of rate constants -- solid state NMR -- magic angle spinning -- NMR of paramagnetic molecules -- contact shifts and shift reagents -- NMR imaging -- contrast agents</p> <p><b>Unit 4: EPR Spectroscopy </b>Principle of EPR -- instrumentation -- total spin Hamiltonian -- presentation of the spectrum -- hyperfine splitting -- super hyperfine structure -- EPR of hydrogen atom -- splitting in isotropic systems involving more than one nucleus -- EPR spectra of free radicals in solution -- methyl radical, benzene anion, p-benzosemiquinone radical anion, p- nitrobenzoate dianion and naphthalene anion -- Evaluation of g and A tensors -- factors affecting the magnitude of g values -- anisotropy -- zero field splitting -- Kramer's theory & degeneracy -- triplet EPR</p> <p><b>Unit 5: Application and advanced EPR </b>Application of EPR in transition metal complexes VO2+ Fe3+ Co2+, Mn2+, Ni2+ and bis-salicylaldimine copper (II) -- Jahn-Teller theory & distortion studies in Cu(II) complexes -- evaluation of spin -- orbital coupling constant -- exchange coupled EPR -- multi resonance EPR -- cw and pulsed EPR and ENDOR -- MEMS and DAVIS -- ESEEM -- HYSCORE -- ESR Spin trapping -- spin labeling -- EPR imaging</p> |
| 650 #0 - SUBJECT | |
| Keyword | Nuclear magnetic resonance. |
| 650 #0 - SUBJECT | |
| Keyword | Electron paramagnetic resonance. |
| 650 #0 - SUBJECT | |
| Keyword | Electron paramagnetic resonance spectroscopy. |
| 856 40 - ONLINE RESOURCES | |
| url | https://www.sciencedirect.com/science/book/9780128136089 |
| 100 1# - MAIN ENTRY--PERSONAL NAME | |
| -- | https://id.oclc.org/worldcat/entity/E39PCjGTYyMxxpfP98tqpjxfYP |
| 758 ## - | |
| -- | has work: |
| -- | Spin resonance spectroscopy (Text) |
| -- | https://id.oclc.org/worldcat/entity/E39PCFBpbRxV6h6vhWgrwhYXVC |
| -- | https://id.oclc.org/worldcat/ontology/hasWork |
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