Numerical Methods and Applications/ (Record no. 176518)
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000 -LEADER | |
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fixed length control field | 00344nam a2200133Ia 4500 |
020 ## - INTERNATIONAL STANDARD BOOK NUMBER | |
International Standard Book Number | 9788131505823 |
040 ## - CATALOGING SOURCE | |
Transcribing agency | CUS |
082 ## - DEWEY DECIMAL CLASSIFICATION NUMBER | |
Classification number | 518 |
Item number | CHE/N |
100 ## - MAIN ENTRY--PERSONAL NAME | |
Personal name | Cheney, Ward |
245 #0 - TITLE STATEMENT | |
Title | Numerical Methods and Applications/ |
Statement of responsibility, etc. | Ward Cheney |
260 ## - PUBLICATION, DISTRIBUTION, ETC. (IMPRINT) | |
Place of publication, distribution, etc. | Australia: |
Name of publisher, distributor, etc. | Brooks/Cole, |
Date of publication, distribution, etc. | 2008. |
300 ## - PHYSICAL DESCRIPTION | |
Extent | 587p. |
505 ## - FORMATTED CONTENTS NOTE | |
Formatted contents note | <br/>BONDING AND MOLECULAR STRUCTURE:The Basics l<br/>Molecular Graphic: Glycine, an organic molecule found :n space 1<br/>1.1 Organic Chemistry and Life 2<br/>1.2 The Structural Theory of Organic Chemistry 3<br/>1.3 Isomers: The Importance of Structural Formulas 4<br/>1.4 Chemical Bonds: The Octet Rule 5<br/>1.5 Wr.ting Lewis Structures 7<br/>1.6 Exceptions to the Octet Rule 9<br/>1.7 Formal Charge 10<br/>1.8 Resonance Theory 13<br/>1.9 Quantum Mechanics and Atomic Structure 18<br/>1.10 Atomic Orbitals and Electron Configuration 20<br/>1.11 Molecular Orbitals 21<br/>1.12 The Structure of Methane and Ethane:sp^ Hybridization 24<br/>THE CHEMISTRY OF... Calculated Molecular Models: Electron Density Surfaces 28<br/>1.13 The Structure ofEthene(Ethylene):sp^ Hybridization 28<br/>1.14 The Structure of Ethyne(Acetylene):sp Hybridization 33<br/>1.15 A Summary ofImportant Concepts that Come from Quantum Mechanics 35<br/>1.16 Molecular Geometry: The Valence Shell Electron Pair Repulsion Model 36<br/>1.17 Representation of Structural Formulas 39<br/>1.18 Applications of Basic Principles 44<br/>FUNCTIONAL GROUPS,INTERMOLECULAR FORCES,AND<br/>INFRARED(IR)SPECTROSCOPY 51<br/>Structure and Function: Organic Chemistry, Nanotechnology,and Bioengineering/<br/>Molecular Graphic: A molecular template for bone growth 51<br/>2.1 Carbon-Carbon Covalent Bonds 52<br/>2.2 Hydrocarbons: Representative Alkanes, Alkenes, Alkynes,and Aromatic<br/>Compounds 52<br/>2.3 Polar Covalent Bonds55<br/>THE CHEMISTRY OF...Calculated Molecular Models: Maps of Electrostatic Potential<br/>2.4 Polar and Nonpolar Molecules 56<br/>Functional Groups 59<br/>AlkyI Halides or Haloalkanes 60<br/>Alcohols 61<br/>Ethers 63<br/>Amines 63<br/>Aldehydes and Ketones 65<br/>Carboxylic Acids, Esters,and Amides 65<br/>Nitriles 67<br/>Summary ofImportant Families ofOrganic Compounds 68<br/>Physical Properties and Molecular Structure 68<br/>Summary ofAttractive Electric Forces 75<br/>the CHEMISTRY OF...Organic Templates Engineered to Mimic Bone Growth 75<br/>2.16 Infrared Spectroscopy:An Instrumental Method for Detecting Functional Groups<br/>2.17 Applications ofBasic Principles 84<br/>ACIDS AND BASES:An Introduction to<br/>Organic Reactions and Their Mechanisms 91<br/>Shuttling tfie Protons/Molecular Graphic: Diamox,a drug that prevents altitude<br/>sickness 91<br/>3.1 Reactions and Their Mechanisms 92<br/>3.2 Acid-Base Reactions 94<br/>THE CHEMISTRY OF...HOMOsand LUMOs in Reactions 97<br/><br/><br/>3.3 Hcterolysis of Bondfi to <br/>3.6 Predicting the Outcome of Acid-Base Reactions 103<br/>3.7 The Relationsivp between Sinjcturo and Ac-d ry 105<br/>3.8 Energy Changes 108<br/>3.9 The Relationship between the ('quilibnum Constant ami tfu- Standard Free Energy<br/>Change.SG" 110<br/>3.10 The Acidity of Carboxylic Acids 111<br/>3.11 The Effect of the Solvent on Aadity 115<br/>3.12 Organic Compounds as Bases 116<br/>3.13 A Mechanism for an Organic Reaction 117<br/>THE CHEMISTRY OF . Carbonic Anhydrasc 118<br/>3.14 Acids and Bases m Nonaqueous Solutions 119<br/>3.15 Acid-Base Reactions and the Synthesis of Deuterium- and<br/>Tritium-Labeled Compounds 120<br/>3.16 Applications of Basic Principles 121<br/>NOMENCLATURE AND CONFORMATIONS<br/>OFALKANES 129<br/>7b Be Flexible or Inflexible - Molecular Structure Makes the Difference/ Molecular<br/>Graphic: A portion of the structure ofdiamond,an exceptionally rigid molecule 129<br/>4.1 Introduction to Alkanes and Cycloalkanes 130<br/>^ THE CHEMISTRY OF... Petroleum Refining 130<br/>4.2 Shapes ofAlkanes 132<br/>4.3 lUPAC Nomenclature ofAlkanes. AlkyI Hahdes. and Alcohols 134<br/>4.4 Nomenclature ofCycloalkanes 141<br/>4.5 Nomenclature of Alkenes and Cycloalkenes 143<br/>4.6 Nomenclature ofAlkynes 145<br/>4.7 Physical Properties ofAlkanes and Cycloalkanes 146<br/>'THE CHEMISTRY OF... Pheromones:Communication by Means of Chemicals 148<br/>4.8 Sigma Bonds and Bond Rotation 148<br/>4.9 Conformational Analysis of Butane 151<br/>4.10 The Relative Stabilities ofCycloalkanes: Ring Strain 153<br/>4.11 The Origin ofRing Strain in Cyclopropane and Cyclobutane:<br/>Angle Strain and Torsional Strain 155<br/>4.12 Conformations ofCyclohexane 156<br/>THE CHEMISTRY OF... Nanoscale Motors and Molecular Switches 159<br/>4.13 Substituted Cyclohexanes:Axial and Equatorial Hydrogen Atoms 160<br/>4.14 Disubstituted Cycloalkanes: Cis-Trans Isomerism 163<br/>4.15 Bicyclic and Polycyclic Alkanes 166<br/>THE CHEMISTRY OF...Elemental Carbon 167<br/>4.16 Chemical Reactions ofAlkanes 168<br/>4.17 Synthesis ofAlkanes and Cycloalkanes 168<br/>4.18 Structural Information from Molecular Formulas and the Index of<br/>Hydrogen Deficiency 169<br/>4.19 NMR Spectroscopy-A Practical Introduction 171<br/>4.20 Applications ofBasic Principles 175<br/>STEREOCHEMISTRY:Enantiomers and Diastereomers 181<br/>The Handedness ofLife/Molecular Graphic: The mirror-image stereoisomers<br/>alanine,a chiral amino acid 181<br/>5.1 The Biological Significance ofChirality 182<br/>5.2 Isonnerism: Constitutional Isomers ana Stereoisomers 183<br/>5.3 Enantiomers and Chiral Molecules 184<br/>5.4 More about the Biological Importance ofChirality 187<br/>5.5 Historical Origin ofStereochemistry 1885.6 Tests for Chirality: Planes of Symmetry 189<br/>5.7 Nomenclature ofEnantiomers: The R.S-Syslcm 190<br/>5.8 Properties ofEnantiomers: Optical Activity 194<br/>5.9 The Origin of Optical Activity 198<br/>5.10 The Synthesis of Chiral Molecules 200<br/>5.11 Chiral Drugs 202<br/>THE CHEMISTRY OF ... Selective Binding of Drug Enantiomers to Left- and<br/>Rigfit-Handed Coiled DNA 203<br/>5.12 Molecules With More than One Chirality Center 203<br/>5.13 Fischer Projection Formulas 207<br/>5.14 Stereoisomerism of Cyclic Compounds 209<br/>5.15 Relating Configurations through Reactions in WIvch No Bonds to<br/>the Chirality Center Are Broken 211<br/>5.16 Separation of Enantiomers: Resolution 213<br/>5.17 Compounds with Chirality Centers Other than Carbon 214<br/>5.18 Chiral Molecules that Do Not Possess a Chirality Center 215<br/>i:<br/>REACTIONS OF ALKYL HALIDES:<br/>Nucleophilic Substitution and Elimination 221<br/>Breaking Bacterial Cell Walls with Organic Chemistry/ Molecular Graphic: Lysozyme 221<br/>6.1 Organic Halides 222<br/>6.2 Nucleophilic Substitution Reactions 224<br/>6.3 Nucleophiles 224<br/>6.4 Leaving Groups 225<br/>6.5 Kinetics ofa Nucleophilic Substitution Reaction: An Sf^2 Reaction 226<br/>6.6 A Mechanism for the Sn2 Reaction 227<br/>6.7 Transition State Theory: Free-Energy Diagrams 228<br/>6.8 The Stereochemistry of Si\i2 Reactions 231<br/>THE CHEMISTRY OF...Lysozyme 234<br/>6.9 The Reaction oftert-Butyl Chloride with Hydroxide Ion:An Si^l Reaction 235<br/>6.10 A Mechanism for the S^l Reaction 236<br/>6.11 Carbocations 237<br/>6.12 The Stereochemistry ofSnI Reactions 239<br/>6.13 Factors Affecting the Rates ofS^l and Sf^2 Reactions 241<br/>. 6.14 Organic Synthesis: Functional Group Transformations Using Sn2 Reactions 250<br/>^ THECHEMISTRY OF...Biological Methylation:A Biological NucleophilicSubstitution<br/>Reaction 251<br/>6.15 Elimination Reactions ofAlky!Halides 253<br/>6.16 The E2Reaction 255<br/>6.17 The El Reaction 256<br/>6.18 Substitution versus Elimination 257<br/>6.19 Overall Summary 260<br/>ALKENES AND ALKYNES-Part I:<br/>Elimination Reactions of AlkyI Halides 269<br/>Cell Membrane Fluidity/Molecular Graphic: cis-9-Octadecenoic acid,an unsaturated<br/>fatty acid incorporated into cell membrane phospholipids 269<br/>7.1 Introduction 270<br/>7.2 The(EHZ)System for Designating Alkene Diastereomers 270<br/>7.3 Relative Stabilities ofAlkenes 272<br/>7.4 Cycloalkenes 274<br/>7.5 Synthesis ofAlkenes via Elimination Reactions 274<br/>7.6 Dehydrohalogenation ofAlkyI Halides 275<br/>7.7 Acid-Catalyzed Dehydration ofAlcohols 280<br/>7.8 Carbocation Stability and the Occurrence ofMolecular Rearrangements 285<br/>7.9 Synthesis ofAlkynes by Elimination Reactions 2887.10 The Acidity of Torm-nal Alkynrs 290<br/>7.11 Replacement of the Acotylcnic Hydrogc-n Atom of Terminal Alkynos 290<br/>7.12 Alkylation of Alkynide Anions Some Gcncrai Principles of Structuio and<br/>Reactivity Illustrated 292<br/>^ 7.13 Hydrogonation of Alkcnes 292<br/>ft 'THE CHEMISTRY OF . Hydrogcnaiion in the Food Industry 293<br/>7.14 Hydrogenation The FufKtion of the Catalyst 294<br/>THE CHEMISTRY OF Homogonoous Asymn^ctric Catalytic Hydrogenation,<br/>Examples Involving i-DOPA.(S)-Nar;roxen. and Aspartame 295<br/>7.15 Hydrogenation of Alkynes 297<br/>_ 7.16 An Introduction to Orcjanic Synthesis 298<br/>!?' the CHEMISTRY or , From the Inorganic!o the Organic 302<br/>ALKENES AND ALKYNES- Part II:<br/>Addition Reactions and Synthesis 311<br/>The Sea:A Treasury of G(o/og'ca//y Active Natural Products / Molecular Graphic:<br/>Dactylyne. a halogcnated marine natural product 311<br/>8.1 Introduction: Addition to Alkcnes 312<br/>8.2 Electrophihc Addition of Hydrogen Hahdes to Alkenes Mechanism and<br/>Mar/covnifcov's Rule 314<br/>8.3 Stereochemistry o/the Ionic Addition to an A/kcnc 319<br/>8.4 Addition of Suifunc Acid to Alkcnes 320<br/>8.5 Addition of Water to Alkenes: Acid-Catalyzed Hydralion 321<br/>8.6 Alcohols from Alkenes through Oxymcrcuration-Demorcuration:<br/>Markovnikov Addition 323<br/>8.7 Alcohols from Alkenes through Hydroboration-Oxidation:<br/>Anti-Markovnikov Syn Hydration 326<br/>8.8 Hydroboration: Syntiiesis ofAlkylboranes 326<br/>8.9 Oxidation and Hydrolysis of Alkyboranes 329<br/>8.10 Summary ofAlkene Hydration Methods 331<br/>8.11 Protonolysis ofAlkyboranes 331<br/>8.12 Electrophilic Addition of Bromine and Chlorine to Alkenes 332<br/>8.13 Stereochemistry of the Addition of Halogens to Alkenes 334<br/>8.14 Halohydrin Formation 337<br/>8.15 Divalent Carbon Compounds:Carbenes 338<br/>8.16 Oxidations ofAlkenes: Syn 1,2-Dihydroxyiation 340<br/>THE CHEMISTRY OF ... Catalytic Asymmetric Dihydroxyiation 342<br/>8.17 Oxidative Cleavage ofAlkenes 343<br/>8.18 Electrophilic Addition of Bromine and Chlorine to Alkynes 345<br/>8.19 Addition of Hydrogen Halides to Alkynes 346<br/>8.20 Oxidative Cleavage of Alkynes 347<br/>.,8.21 Synthetic Strategies Pevisited 347* ... n<br/>THE CHEMISTRY OF ... Cholesterol Biosynthesis: Elegant and Familiar Reactions<br/>in Nature 350<br/>NUCLEAR MAGNETIC RESONANCE AND MASS SPECTROMETRY:<br/>Instrumental Methods for Structure Determination 363<br/>A Thermos at Liquid Helium/Molecular Graphic: 1-chloro-2-propanol 363<br/>9.1 Introduction 364<br/>9.2 Nuclear Magnetic Resonance(NMR)Spectroscopy 364<br/>9.3 Interpreting Proton NMR Spectra 369<br/>9.4 Nuclear Spin: The Origin ofthe Signal 371<br/>9.5 Detecting the Signal: Fourier Transform NMR Spectrometers 373<br/>9.6 Shielding and Deshielding ofProtons 374<br/>9.7 The Chemical Shift 376<br/>9.8 Chemical Shift Equivalent and Nonequivalent Protons 377<br/>9.9 Signal Splitting: Spin-Spin Coupling 379<br/>9.10 Proton NMR Spectra and Rate Processes 3889.11 Carbon-13 NMR Spectroscopy 390<br/>9.12 Two-Dimensional(2D)NMR Techniques 396<br/>i?" THE CHEMISTRY OF... Magnetic Resonance Imaging m Medicine 399<br/>9.13 An Introduction to Mass Spectrometry 399<br/>9.14 Formation ofIons: Electron Impact lonization 400<br/>9.15 Depicting the Molecular Ion 400<br/>9.16 Fragmentation 401<br/>9.17 Determination of Molecular Formulas and Molecular Weights 407<br/>9.18 Mass Specfrometer /nstrument Designs 412<br/>9.19 GC/MS Analysis 415<br/>9.20 Mass Spectrometry of Biomolecules 416<br/>REACTIONS INVOLVING RADICALS 427<br/>Radicals in Biology. Medicine,and Industry/Molecular Graphic:<br/>Nitric oxide and Cia/i's® 427<br/>10.1 Introduction 428<br/>10.2 Homolytic Bond Dissociation Energies 429<br/>10.3 The Reactions ofAlkanes with Halogens 433<br/>10.4 Chlorination of Methane: Mechanism of Reaction 435<br/>10.5 Chlorination of Methane:Energy Changes 437<br/>10.6 Halogenation of Higher Alkanes 443<br/>10.7 The Geometry ofAlkyI Radicals 446<br/>10.8 Reactions that Generate Tetrahedral Chirality Centers 446<br/>10.9 Radical Addition to Alkenes: The Anti-Markovnikov Addition ofHydrogen Bromide 449<br/>10.10 Radical Polymerization ofAlkenes: Chain-Growth Polymers 451<br/>10.11 Other Important Radical Reaaions 455<br/>THE CHEMISTRY OF... Callcheamidn A]':A Radical Device for Slicing the Backbone<br/>of DNA 456<br/>THE CHEMISTRY OF...Antioxidants 458<br/>THE CHEMISTRY OF... Ozone Depletion and Chlorofluorocarbons(CFCs) 459<br/>SPECIAL TOPIC A: CHAIN-GROWTH(ADDITION)POLYMERS 464<br/><br/>ETHERS AND ALCOHOLS 469<br/>Molecular Hosts/Molecular Graphic: Monens/n sodium salt, an antibiotic that<br/>transports ions across cell membranes 469<br/> |
942 ## - ADDED ENTRY ELEMENTS (KOHA) | |
Koha item type | General Books |
Withdrawn status | Lost status | Damaged status | Not for loan | Home library | Current library | Shelving location | Date acquired | Full call number | Accession number | Date last seen | Date last checked out | Koha item type |
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Central Library, Sikkim University | Central Library, Sikkim University | General Book Section | 29/08/2016 | 518 CHE/N | P31518 | 28/02/2017 | 28/02/2017 | General Books |